使用mmap时整数存储为不正确的值

我正在编写一个程序，该程序将使用mmap将结构数组写入文件。问题是第三个整数值（左）未正确存储。通过查看文件时od，字节left似乎向左移了一个字节。例如...

|loc            |value  |left          |right          |extra bytes?
001 000 000 000 103 120 000 000 000 003 000 000 000 004 000 000 //expected
001 000 000 000 103 120 000 000 003 000 000 000 004 000 000 000 //result

typedef struct{
    int32_t loc;
    char value[2];
    int32_t left;
    int32_t right;

}Node;

Node newNode(int i);

int main(int argc, char *argv[])
{
    int i;
    int fd;
    int result;
    Node *map;  /* mmapped array of int's */

    int filesize = strtol(argv[2], NULL, 10) * sizeof(Node);
    int numvalues = filesize / sizeof(Node);

    fd = open(argv[1], O_RDWR | O_CREAT | O_TRUNC, (mode_t)0600);
    if (fd == -1) {
        perror("File failed to open");
        exit(1);
    }

    //I dont know why this makes it work but we need to move the file pointer around for some reason.
    result = lseek(fd, filesize-1, SEEK_SET);
    if (result == -1) {
        close(fd);
        perror("Error calling lseek()");
        exit(2);
    }

    // same with this
    result = write(fd, "", 1);

    /* Now the file is ready to be mmapped.
    */
    map = (Node *) mmap(0, filesize, PROT_READ | PROT_WRITE, MAP_SHARED, fd, 0);
    if (map == MAP_FAILED) {
        close(fd);
        perror("Error mmapping the file");
        exit(4);
    }


    for (i = 0; i <numvalues; ++i) {
        map[i] = newNode(i);         /* here is where I save the data */
    }

    munmap(map, filesize);
    close(fd);
    return 0;
}

Node newNode(int i) { /*This method is where the structs are made*/
    Node n;
    n.left = i * 2 + 1;
    n.right = i * 2 + 2;
    n.value[0] = (char)(rand() % ('A' - 'Z') )+ 'A';
    n.value[1] = (char)(rand() % ('A' - 'Z') )+ 'A';
    n.loc = i;

    printf("%d, %d, %c, %c, %d\n", n.left, n.right, n.value[0], n.value[1], n.loc);

    return n;
}

同样，为什么某些整数保存为little endian，而另一些保存为big endian。